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By Krause W.

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47 Abstract This review presents a comprehensive overview of the most significant developments in the chemistry of technetium and rhenium complexes anchored by heterofunctionalized phosphines and by hard and soft scorpionates. The main goal is to provide the reader with chemical, radiochemical and biological knowledge which is expected to enhance the application of these types of compounds in the development of target-specific radiopharmaceuticals. In the introductory section, a short historical outlook is presented to introduce the few 99m Tc radiopharmaceuticals based on phosphorus- and boron-containing ligands already in clinical use.

47 Abstract This review presents a comprehensive overview of the most significant developments in the chemistry of technetium and rhenium complexes anchored by heterofunctionalized phosphines and by hard and soft scorpionates. The main goal is to provide the reader with chemical, radiochemical and biological knowledge which is expected to enhance the application of these types of compounds in the development of target-specific radiopharmaceuticals.

70 71 71 74 75 75 Concluding Remarks and Perspectives . . . . . . . . . . 79 . . . . . . . . . . . . . . . . . . . 80 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47 Abstract This review presents a comprehensive overview of the most significant developments in the chemistry of technetium and rhenium complexes anchored by heterofunctionalized phosphines and by hard and soft scorpionates.

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